Detection and characterisation of intergranular stresscorrosion cracking on austenitic stainless steel article pdf available in materials and corrosion 638. Transgranular, granulated, and intergranular stress corrosion. Paper presented at stainless steel world 2005 conference, maastricht, the netherlands, 810 november 2005. Transgranular, granulated, and intergranular stress corrosion cracking in aisi 304 ss h. Cracking of stainless steel nozzle sleeve metallurgical. Another form known as sulphide stress corrosion cracking sscc is associated with hydrogen sulphide in oil and gas exploration and production. A kind of stainless steel in a number of media have good corrosion resistance, but in some other medium, but may occur due to low chemical stability and corrosion. Feb 06, 2011 intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the bulk of t he grains remain largely unaffected igc is associated. Intergranular attack is also a quite rare form of corrosion. Influence of chromium depletion on intergranular stress. Transgranular, granulated, and intergranular stress. Dec 19, 2019 intergranular stress corrosion cracking igscc is a type of corrosion due to applied forces on the granular boundaries of a material. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will.
It lances fine coals contain corrosive elements like. Effects of hydrogen peroxide on intergranular stress corrosion cracking of stainless steel in high temperature water, iv journal of. Potentiostatic slow strain rate tests ssrt were performed to investigate the susceptibility to intergranular stress corrosion cracking igscc of type 304l uns s30403 stainless steel ss in 299 c water, focusing on corrosion potential and the degree of sensitization. Grain boundary precipitation, notably chromium carbides in stainless steels, is a well recognized and accepted mechanism of intergranular corrosion. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Stainless steel corrosion pitting corrosion crevice. Intergranular stress corrosion cracking igscc is more common than transgranular scc. Different kinds of corrosion on stainless steel montanstahl. Intergranular stress corrosion cracking an overview. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking of an austenitic stainless steel. This type of decomposition can break down the mechanical properties of steel in days rather than months or years. Stress corrosion cracking of an austenitic stainless steel in. Intergranular stress corrosion cracking scc mechanism in sensitized stainless steel type 304 was investigated experimentally.
Transgranular stress corrosion cracking tgscc is the same as igscc, but. Crack propagation depends on the frequency with resistant triple junctions are encountered by the crack tip, thus both grain size and the grain boundary. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2. In this chapter, the conditions for the occurrence of scc are first introduced. Chiba, influence of carbide precipitation and rolling direction on intergranular stress corrosion cracking of austenitic stainless steels in hydrogenated hightemperature water, corrosion. Intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel. Grain boundary control for improved intergranular stress corrosion cracking resistance in austenitic stainless steels j marrow, d engelberg, a jivkov, p wood, l. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Effect of grain boundary network on the intergranular stress. Intergranular attack in welded stress corrosion resistant stainless steels satisfactory stress corrosion resistance is obtained using arc welding and, depending on the base metal, type 376. Effects of hydrogen peroxide on intergranular stress. Intergranular stress corrosion cracking in rbmk reactors to assist countries operating rbmk reactors in addressing the issue in austenitic stainless steel 300 mm diameter piping. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion.
The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steel electrolyte interface, which are formed by the applied cathodic current to protect the structure 71. Intergranular corrosion might occurs in steel alloys with chromium, niobium or titanium, and in aluminium alloys with cooper or magnesium. Intergranular corrosion stainless steel tubing manufacturer. Intergranular stress corrosion cracking initiation model of austenite. Intergranular stress corrosion cracking scc of pipelines has been known to cause. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Chloride stress corrosion cracking in austenitic stainless. Pdf the influence of material factors on the intergranular stress corrosion cracking igscc susceptibility of austenitic stainless steels under. Chloride stress corrosion cracks were also found at the corrosion sites.
Failure analysis of corrosion on stainless steel fasteners. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking. However, with modern steel making methods, it has become possible. Observations of intergranular stress corrosion cracking in. Austenitic stainless steels such as types 304 and 316 are susceptible to intergranular corrosion igc and intergranular stress corrosion cracking igscc when heat treated at temperatures in the range of 450sup 0 to 850sup 0c. Intergranular stress corrosion cracking has occurred in bwr environments in nonsensitised, coldworked austenitic stainless steel materials. Recognize the mechanism for igscc and the conditions that make igscc more likely. Igscc of bwr low carbon and stabilized stainless steels, late 1980s. On the mechanism of intergranular stress corrosion cracking of. Chromium carbides can be precipitated if the stainless steel is sensitized in the temperature range 550850c 10201560f, for example during heat treatment or welding. The problem of corrosion the special case of stainless steel types of corrosion general corrosion localized corrosion intergranular corrosion pitting corrosion crevice corrosion galvanic corrosion stress corrosion cracking factors affecting corrosion corrosion testing intergranular corrosion pitting and crevice corrosion stress corrosion cracking.
For the study, a criterion for the rate of intergranular corrosion igc for detecting the susceptibility to intergranular stress corrosion cracking igscc in hightemperature oxygenated pure water was established by quantitatively evaluating the results from a modified astm a262e test. Intergranular corrosion of stainless steel often occurs after an incorrect heat treatment, and the heat treatment that causes the intergranular corrosion tendency of stainless steel is. So, a stainless steel corrosion can not have all media. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. Intergranular stress corrosion cracking resistance of. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. Pdf detection and characterisation of intergranular stress. In areas where corrosion is a concern, stainless steel products offer value and protection against these threats. Effects of hydrogen peroxide on intergranular stress corrosion cracking of stainless steel in high temperature water, i journal of nuclear science and technology.
Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. In aqueous environments, metals may be exposed to not only uniform corrosion, but also to various types of local corrosion including pitting, crevice, intergranular, stress, and galvanic corrosion. Stress corrosion cracking scc is a common issue with many specialty alloys. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Nrc position on igscc in bwr austenitic stainless steel piping generic letter 8801 intergranular stress corrosion cracking. Jul 18, 2008 nondestructive threedimensional mapping of grain shape, crystallographic orientation, and grain boundary geometry by diffraction contrast tomography dct provides opportunities for the study of the interaction between intergranular stress corrosion cracking and microstructure. Characterization of intergranular stress corrosion cracking of 304. Crack growth is driven by the inelastic deformation at the sharp crack tip. The photos above show the microstructure of a type 304 stainless steel. Intergranular stress corrosion cracking of austenitic stainless steel piping in bwrs has been a major safety concern since the early seventies. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. A cracked nozzle sleeve stub from a chemical processing vessel of the proprietary vaporizer system was analyzed to determine the cause of cracking.
Inter granular corrosion can be detected by ultrasonic and eddy current methods. Cracks initiated at intergranular corrosion penetrations propagating by corrosion assisted fatigue. Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Considering weld decay and knife line attack kla, intergranular corrosion takes place when welding operations occurs in stainless steels. The environmental and metallurgical factors in the intergranular stress corrosion cracking of austenitic stainless steel at temperatures below 100 c has been examined. Intergranular corrosion facts and how to reduce the risk. This type of corrosion was previously a potential risk for stainless steel because of its high carbon content. The intergranular cracks and grain boundary gb network of a gbengineered 316 stainless steel after stress corrosion cracking scc test in high temperature high pressure water of reactor. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Elements of corrosion damaging stainless steel stainless. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. This paper evaluates the resistance to intergranular stress corrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. They react with the carbon to form the corresponding carbides, thereby preventing chromium.
Rare, yet severe, stress corrosion cracking is the result of tensile stress combined with elevated temperature, and moisture. Scc testing was conducted under a constant load, and microscopic strains on a smooth surface were measured in situ by the digital image correlation technique. Investigation on nucleation of intergranular stress. Intergranular stress corrosion cracking initiation model of austenite stainless steels used in bwrs for optimized water chemistry control. Gooch introduction although austenitic stainless steels. The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking.
Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. A stress corrosion crack was grown through a volume of sensitized austenitic stainless steel mapped with dct and. In nickel alloys and austenitic stainless steels, where chromium is added for corrosion resistance, the mechanism involved. Observations of intergranular stress corrosion cracking in a. Grain boundary control for improved intergranular stress. Intergranular stress corrosion cracking igscc is the progressive nucleation and growth of cracks by localized corrosion along the grain boundaries in metals in the presence of stress or strain. At a highly increased rate, it is unlike that of other varieties. Pdf intergranular cracking of aisi 316ng stainless steel. The intergranular stress corrosion cracking of sensitized 304 stainless steel in na2s2o3 solutionwas detected by electrochemical noise en. This study evaluates the nucleation criterion for intergranular stress corrosion cracking scc on a smooth surface of type 304 austenitic stainless steel from a mechanical viewpoint. The initiation period and site of intergranular cracks were estimated from the change in the microscopic strain distribution near grain boundaries gbs.
Test specimens are installed in a stainless steel autoclave which. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Sensitization, intergranular attack, stress corrosion. Postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels. The use of 316l would be more resistant to crevice corrosion attack. This occurs at temperatures between about 450850 c. Postweld heat treatment to avoid stress corrosion cracking. Consequently, intergranular cracking observed at the lower temperature, that is, 408 k for type 304 and 316 steels is due to grain boundary martensiteinduced hydrogen embrittlement he and transgranular cracking for type 304 and 316 steels at higher temperatures at 416 and 428 k and for 310 steel is ascribed to stress corrosion cracking in. This type of failure is known as stress corrosion cracking, often abbreviated to scc. In the presence of tensile strength, cracking may occur along grain boundaries and this type of corrosion is frequently called interranular stress corrosion cracking igscc or simply intergranular corrosion cracking. Why is chloride stress corrosion cracking transgranular.
Most notably, pitting and cracking in this instance had initiated andor. Intergranular attack is caused by the formation of chromium carbides fe,cr23c6 at grain boundaries, reducing the chromium content and the stability of the passive layer on stainless steels. Fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel. This type of attack results from local differences in composition, such as coring commonly encountered in alloy castings. The interaction of corrosion fatigue and stresscorrosion. Intergranular stress corrosion cracking of welded steel twi. Intergranular stress corrosion cracking of austenitic. In order to determine effects of hydrogen peroxide on stress corrosion cracking of structural materials in the primary cooling systems of boiling water reactors, a high temperature high pressure water loop with controlled hydrogen peroxide concentrations and lower possible oxygen concentrations has been fabricated. Stress corrosion cracking international institute of.
It is as a result of chromium depletion, mainly due to the precipitation of chromium carbides in the grain boundaries. Babout, n stevens materials performance centre, university of manchester, oxford rd, manchester, uk tel. Pdf intergranular stress corrosion cracking behavior of. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Use of stabilized grades alloyed with titanium or niobium. Nrc position on igscc in bwr austenitic stainless steel. Oct 23, 2014 which materials can be affected by intergranular corrosion. In the case of transgranular scc, the cracks advanced across the specific crystal planes with low indices 70. Intergranular cracking proceeds along the grain boundaries whereas transgranular cracking does not have preferences for boundaries 69. Commercial titanium can suffer intergranular stress corrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. Scc can occur typically in hot water tanks or swimming pools. Galvanic corrosion intergranular corrosion intergranular corrosion of stainless steel tubes corrosion resistant stainless steel tube corrosion resistance of.
What is intergranular stress corrosion cracking igscc. There are two modes of stress corrosion cracking in austenitic stainless steels, namely intergranular and transgranular stress corrosion cracking, i. Cracking in the heat affected zone of stainless steel piping due to chromium depletion and chromium carbide formation at the grain boundaries was early a problem for many plants. Intergranular attack in welded stresscorrosion resistant stainless steels satisfactory stress corrosion resistance is obtained using arc welding and, depending on the base metal, type 376. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. Corrosion assisted fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel summary. Stress corrosion cracking stress corrosion cracking is a failure mode caused by a combination of a susceptible material, stresses and an aggressive environment, figure 1. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be susceptible to intergranular corrosion or intergranular stress corrosion cracking. I have observed transgranular stress corrosion cracking in a coal injection lance pipe made of 309s grade of austenitic stainless steel.
Intergranular stress corrosion cracking igscc is a type of corrosion due to applied forces on the granular boundaries of a material. Solomon 1 general electric corporate research and development center, p. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. Intergranular corrosion is sometimes also called intercrystalline corrosion or interdendritic corrosion. Stress corrosion cracking odonnell consulting engineers.
1390 7 202 399 848 828 1115 611 394 1475 569 1506 1053 1448 165 288 461 1324 821 609 1083 359 924 303 809 849 658 863 262 1487 182 110 1423 259 91 412 295 433 316 358